In the world of water technology, sometimes the most significant discoveries come from the tiniest of particles. Talie Zarei’s journey into the realm of molecular limescaling structures took her instead to the realm of nanobubbles – a blessing in disguise.
“I’ve always been interested in science, but I only got into physics later. I enjoyed applied physics on water during my MSc thesis and continued as a researcher.” Her move to Wetsus for her PhD felt like a calling. “When Wetsus opened a PhD vacancy, it felt like the universe was calling me,” she says with a smile. And a perfect fit, she was.
The people behind the science, and the science behind the people.
Talie’s research focuses on the ever-changing state of particles before they start crystalizing – dynamic pre-nucleation clusters that initiate calcium carbonate formation. “DOLLOPs are nanoscale structures that form before calcium carbonate crystallizes into limescale,” Talie explains. “Their existence was only recently discovered, challenging classical crystallization theories, which assume that solids form directly from dissolved charged particles.”
The importance of this research extends beyond academic curiosity. Understanding and controlling DOLLOPs could have practical applications in mitigating calcium carbonate buildup in everyday items. “From water kettles to membranes, pipes, and showers, managing limescale is a common issue.” Studying these elusive structures presents unique challenges. “Characterizing DOLLOPs has to be done in situ, in their native liquid environment at minuscule concentrations,” Talie says. To overcome this hurdle, she employed an innovative approach using multi-angle light scattering.
Talie’s journey took an unexpected turn when her initial experiments yielded puzzling results. “I was very excited at first as I soon saw results,” she recalls. “But then I noticed similar patterns in controls without calcium, and the structures were larger than expected. I was devastated, thinking I had spent so long to get to that point for nothing.”
However, this apparent setback led to a fascinating discovery. “We realized I was measuring nanobubbles – tiny CO2 bubbles in solution that are impossibly small and shouldn’t exist naturally in liquid, but somehow do!”
These nanobubbles opened a new avenue of research. The bubbles are exciting because they are charged and interact with pre-nucleation clusters and nanodroplets, slowing down the solidification of calcium carbonate. “Even more intriguing, we found they are controllable with magnetic fields– we can manipulate their charge, size, and other properties.” As Talie continues her research, she’s contributing to our understanding of water at the nanoscale level. Her work with DOLLOPs and the unexpected discovery of manipulable nanobubbles may lead to innovative chemical-free solutions for water treatment and beyond.